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For metal roofs, a high-solids polyether or silicone sealant is best. Many of these are pigmented to match popular roof colors so they blend in and form a solid seal.
Understanding the Components of a Metal Roof
Strictly speaking, metal roofs do not require gutters because metal roofs themselves are resistant to the damage gutters are designed to prevent. However, gutters do play a significant role in protecting other parts of your property.
The short answer is no, a metal roof does not need to be grounded. In most cases, you will not incur additional risk if you don’t ground it. Metal does conduct electricity. But when dealing with a full roof, a lightning strike would ground out through the structure, causing no more harm than non-metal roofs would.